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 Post subject: Re: Source of Potassium
PostPosted: Nov 26th, '11, 14:37 
sendthis wrote:
The same way sodium chloride does. How it works is besides the point.


But Sodium Chloride doesn't soften water either... or not in any sense I know of.. chemically or otherwise...

Quote:
From Wikipedia... but you can find the same information in numerous other sites.

Regeneration

The resin's capacity is gradually exhausted and eventually it contains only divalent ions, Mg2+ and Ca2+ for cation exchange resins, and SO42- for anion exchange resins. At this stage, the resin must be regenerated. If a cationic resin is used (to remove calcium and magnesium ions) then regeneration is usually effected by passing a concentrated brine, usually of sodium chloride or potassium chloride, or hydrochloric acid solution through them. For anionic resins, regeneration typically uses a solution of sodium hydroxide (lye) or potassium hydroxide. The salts used for regeneration are released into the soil or sewer.

Don't know what resin is being referred to in the above quote... but it would appear to be some sort of RO type of filter.... as it refers to removal of Calcium & Magnesium ions... usually found in "hard water"....

So yes... an RO unit... charged with an appropriate "resin"... through ionic exchange... will "soften" water...

But the "brine, usually of sodium chloride or potassium chloride" ... is used to recharge the resin...

It doesn't "soften" the water at all...

Quote:
Unless this is an issue of both of us speaking english but the words meaning different things to us. Water softener is a misnomer, because it doesn't soften the water, it's just what we use in vernacular here in the US referring to sodium chloride or potassium chloride when used for the water softening system.


Then, sorry... but the use of the term "soften"... when applied to the use of sodium, or potassium chloride... to recharge the ioninc filter in an RO unit/filter...

Is a complete misnomer...


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 Post subject: Re: Source of Potassium
PostPosted: Nov 27th, '11, 00:57 
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RupertofOZ wrote:
Is a complete misnomer...


We'll talk in circles if we discus semantics and Australian versus British versus American English. It's just what we call it. Unless I'm wrong, so if someone in the US can tell me where/how I'm using it wrong. I'm not totally comfortable with lots of terms we use because they're misleading, but it many languages, you can't always take the meanings using direct and literal translation.

Here in the US, hardware stores sell big packages of water "softener" which is NaCl or KCl.

Regardless of what you call it or how, at least here in the states, Potassium Chloride is sold in giant bags for water TREATMENT.

Maybe you also classify it in two different ways. We have "temporary" hardness (referring to carbonate compounds) and "permanent" hardness (typically referring to sulphates/chlorides). It's all very confusing even to us.

The water softener systems using NaCl or KCl are used for temporary hardness.

Again, that's just how the words are used here. I can't imagine though that such systems don't exist in Australia (by some other name) that do the same thing. Either way, KCl is a cheap and abundant source of potassium and research has shown it's safe for fertilizer use.


Last edited by sendthis on Nov 27th, '11, 01:13, edited 1 time in total.

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 Post subject: Re: Source of Potassium
PostPosted: Nov 27th, '11, 01:02 
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RupertofOZ wrote:
But Sodium Chloride doesn't soften water either... or not in any sense I know of.. chemically or otherwise...

So yes... an RO unit... charged with an appropriate "resin"... through ionic exchange... will "soften" water...

But the "brine, usually of sodium chloride or potassium chloride" ... is used to recharge the resin...

It doesn't "soften" the water at all...



Hmm.. maybe you guys don't use this type of system over there? I personally have never cared to use these systems but they're kind of common over here. The only reason I know anything about them is because the fish I keep prefer soft water and people ask all the time if they can use the above mentioned systems.

<shrug>

I'm kind of curious now if it is used in Australia. If so, maybe it's just not common or it goes by a different name. It's so common in my area that they're in about every gas station sitting on pallets (not de-icing salts either - which this time of year are out as well).


Last edited by sendthis on Nov 27th, '11, 01:15, edited 1 time in total.

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 Post subject: Re: Source of Potassium
PostPosted: Nov 27th, '11, 01:12 
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Mr Damage wrote:
No disrespect to those that sat at the front during science class, but... CAN SOMEONE EMAIL ME PANADOL?... MY HEAD HURTS!!! :support:


I've found numerous sources about this in the past but I did a quick Google Search for you and provided you the quotes and links. I was aware of KCl in "softeners" and I wanted to use it as fertilizer for my plants. We also use it here in the Northern US as "pet and lawn" safe de-icers (along with the more expensive Calcium Chloride w/ Sodium Chloride being the cheapest).

Based on the below, I would say it's safe. Chloride also offsets nitrite poisoning (that's why people tell you to add NaCl, it's not the sodium it's the chloride). So as many people here seem to add a lot of NaCl to their systems, KCl has the benefit of doing the same thing AND providing potassium fertilizer to your plants. I'm not an expert though, so you can draw your own conclusions from the below links....

"Potassium chloride (KCl), known also as muriate of potash (MOP), is the
most widely used source of potassium for agricultural crops."
http://www.ipipotash.org/udocs/1.%20Tab ... uction.pdf

"Potassium chloride (KCl), also called muriate of potash, is the most commonly used potassium fertilizer. It is a relatively inexpensive nutrient, and deficiencies can often be corrected with moderate rates of application. As a result, correcting a potassium deficiency can result in excellent economic returns."
http://www1.agric.gov.ab.ca/$department ... l/agdex917


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 Post subject: Re: Source of Potassium
PostPosted: Nov 27th, '11, 01:16 
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sendthis wrote:
It's so common in my area that they're in about every gas station sitting on pallets (not de-icing salts either - which this time of year are out as well).


hehe... or should I say petrol station? Since technically, petroleum fuel isn't a 'gas' ;)


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 Post subject: Re: Source of Potassium
PostPosted: Nov 27th, '11, 08:43 
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Mr Damage wrote:
Quote:


No disrespect to those that sat at the front during science class, but... CAN SOMEONE EMAIL ME PANADOL?... MY HEAD HURTS!!! :support:

In english please... Is it fish and plant friendly?... and what will it do to the pH?

I know about the individual benefits of Potassium to plants and Chloride to the fish... but will this be okay in an AP system?

Cheers!


What He said :laughing3:
Is M.O.P. fish safe ? If so, it would be a cheaper source of pottasium.
What rates would you use?
Cheers


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 Post subject: Source of Potassium
PostPosted: Nov 27th, '11, 08:58 
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Mr Damage wrote:
Hi CGD,

If your system pH is low and needs buffering up with lime etc from time to time, then you can use the Eco-rose (Potassium bicarbonate) in the same way as the lime. Simply add it to the water in your system, it will buffer the pH up and add Potassium at the same time.

I would add it at a rate of one well heaped teaspoon per 1000 litres (I've read of people adding more than that, but best to err on the side of caution). Mix the teaspoon of Eco-rose into a bucket of water from your system (or top-up water about to be added), make sure it's thoroughly dissolved, then add to your system by pouring a 1/4 of the bucket of water into your system with each bell siphon cycle, or every 15 minutes or so in a timed or CF system. Check the system pH a few hours later, and if you still need to raise the pH further then use lime as per your usual method.

Don't use it each time you buffer your pH up, you can have too much Potassium, only add when your plants show signs of needing it, or maybe every couple of months as a precaution if you are growing fruiting/flowering plants

I added some to my little AP system a few days ago for the first time ever and I can see a difference in the plants already, especially my Capsicum seedling and Asian greens seedlings. I have two varieties of lettuce, one variety has gotten noticeably greener in only a few days.

Cheers.

geez that's technical, I just chuck a tablespoon ish amount into the ft, it foams a little but not for long :)


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 Post subject: Re: Source of Potassium
PostPosted: Nov 27th, '11, 12:45 
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2 grams per 100L of KCl should yield 10.49 ppm Potassium. Your target potassium level really depends on the plants, but I would keep it around 10ppm if not sure.

As a way to compare,...
2.00g per 100L of KCl is about 10.5ppm Potassium
2.71g per 100L of KNO3 is about 10.5ppm Potassium and
2.34g per 100L of KSO4 is about 10.5ppm Potassium

So adjust appropriately if replacing your other Potassium sources with KCl. From what I've read here, the nitrates in aquaponics setups are high enough that you can do without KNO3. The numbers are also close enough that a 1:1 replacement isn't going to be a big concern.

2.71 KCl is 14.21 ppm Potassium. Feel free to check my numbers, use at your own risk.


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 Post subject: Re: Source of Potassium
PostPosted: Nov 27th, '11, 16:03 
sendthis wrote:
Maybe you also classify it in two different ways. We have "temporary" hardness (referring to carbonate compounds) and "permanent" hardness (typically referring to sulphates/chlorides). It's all very confusing even to us.

The water softener systems using NaCl or KCl are used for temporary hardness.


Close... but no cigar...

I suspect the terms "temporary" hardness... and "permanent" hardness... are those used by.. and/or conveyed...by aquaria shops...

The preferred terms are "carbonate" hardness.. and "general" hardness...

Carbonate hardness is a measure of the buffering capacity of the water... associated with the carbonate content.. and usually calcium carbonate...

As this... through nitrification.. is eventually exhausted... (hence pH drops)... it could be said to be "temporary"...

General hardness... is the meausre of the positive metallic ions in water... (often called "hard" water)... usually Calcium, Magnesium and Iron... and are not generally depleted/exhausted... hence they could be called "permanent"...

However it is not correct to attribute "permanent", or more correctly "general" hardness... to the measure of sulphates and/or chlorides....

Think about it... it wouldn't make sense to try and soften.. reduce the hardness... of something measured by the content of chloride ions... by adding chloride ions... :wink:

Nor will adding chloride ions.... Sodium, or Potassium... have any effect on the "carbonate" buffering... or carbonate hardness... of your water...

Snake oil would probably be just as ineffective... :wink:

And yes... the chloride ion is effective is de-icing....

Quote:
Either way, KCl is a cheap and abundant source of potassium and research has shown it's safe for fertilizer use.


No dispute about that...

But be wary of over-use... it will raise your salinity if you were to use it too often...

And Potassium is generally only needed as a "boost" at flowering/seeding/fruiting stages of plant growth...


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 Post subject: Re: Source of Potassium
PostPosted: Nov 27th, '11, 23:22 
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RupertofOZ wrote:
I suspect the terms "temporary" hardness... and "permanent" hardness... are those used by.. and/or conveyed...by aquaria shops...

The preferred terms are "carbonate" hardness.. and "general" hardness...


This is true. I'll leave understanding semantics to the linguists.

Btw, did you just Google that or did you know all along? Like I said, the effectiveness of such systems was not the point of my post. That's just what they're called. The -point- of my post was that KCl is readily available.


Last edited by sendthis on Nov 27th, '11, 23:28, edited 1 time in total.

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 Post subject: Re: Source of Potassium
PostPosted: Nov 27th, '11, 23:26 
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RupertofOZ wrote:
Snake oil would probably be just as ineffective... :wink:




Is this something you know or something that you're hypothesizing? The fundamental chemistry of what they're doing is true. The effectiveness is not something I can speak to since I don't use one or care to.


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 Post subject: Re: Source of Potassium
PostPosted: May 31st, '14, 23:12 
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My head is spinning after trying to figure out this post. Thanks for all the tips on adding potassium to aquaponic systems, but does any one have a way to add potassium to a system with high pH (8.1) and high salinity (2.9 ppt)?

My system has been buffering at 8.1 for a while now, and I am trying to lower the pH, at the same time my salinity is high because I was treating my fish for ich and fin rot. Now I need to add potassium as my plants seem to have potassium deficiency. Potassium BiCarbonate, Potassium Hydroxide, and Potassium Chloride are all out of the questions unfortunately?

Oh yeah, and I don't have access to commercial fertilizers such as Maxicrop and others.

Cheers


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 Post subject: Re: Source of Potassium
PostPosted: Jun 1st, '14, 01:49 
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hi all

i made potassium carbonate by burning banana peels and put the ash in bottle with water ( PH IS 11) , will it help the plants to get it if i spray that liquid on the leaves.?


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 Post subject: Re: Source of Potassium
PostPosted: Jun 1st, '14, 06:01 
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kij2 wrote:
Potassium BiCarbonate, Potassium Hydroxide, and Potassium Chloride are all out of the questions unfortunately?

Cheers


What about potassium sulfate? Those chloride ions build up - but plants need sulphur.


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 Post subject: Re: Source of Potassium
PostPosted: Jun 1st, '14, 11:59 
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kij2 wrote:
My head is spinning after trying to figure out this post. Thanks for all the tips on adding potassium to aquaponic systems, but does any one have a way to add potassium to a system with high pH (8.1) and high salinity (2.9 ppt)?

My system has been buffering at 8.1 for a while now, and I am trying to lower the pH, at the same time my salinity is high because I was treating my fish for ich and fin rot. Now I need to add potassium as my plants seem to have potassium deficiency. Potassium BiCarbonate, Potassium Hydroxide, and Potassium Chloride are all out of the questions unfortunately?

Oh yeah, and I don't have access to commercial fertilizers such as Maxicrop and others.

Cheers
Are you sure you have a Potassium deficiency?... At 3 parts per thousand of salt many plants will start to show signs of Sodium toxicity, which can present very similar symptoms to Potassium deficiency, ie: Yellowing between the veins and along the leaf margins, as well as necrosis of the leaf margins.

Quote:
What about potassium sulfate? Those chloride ions build up - but plants need sulphur.
Potassium Sulphate may be an option. I've been told that Sulphate based products should reduce pH, but I recently added Manganese Sulphate to my system and it did nothing to the pH. So Potassium Sulphate may be an option for adding Potassium in this situation where kij2's pH is high... if it actually is a Potassium deficiency.


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